Protons are kryptonite to super material graphene

The batteries of electric cars like this BMW i3 could be revolutionised with the new discovery. (Supplied)

The batteries of electric cars like this BMW i3 could be revolutionised with the new discovery. (Supplied)

Impermeable to gases and liquids, the super material graphene can be pierced by one type of subatomic particle, according to a surprise discovery hailed Wednesday as a breakthrough for fuel cell technology.

The world’s thinnest material, but stronger than steel, graphene acts as a barrier even to the smallest of atoms, hydrogen – but has now been shown up to have a chink in its armour for protons. Protons, with neutrons, make up the nuclei of atoms, the building blocks of matter.

“The discovery could revolutionise fuel cells and other hydrogen-based technologies as they require a barrier that only allow protons – hydrogen atoms stripped of their electrons – to pass through,” said a statement from Manchester University, whose researchers took part in the work.

The world’s thinnest material made of carbon just one atom thick, graphene’s impermeability makes it an effective barrier in coatings and packaging materials.

Lifetime of the universe
It would take the lifetime of the universe for hydrogen, the smallest of all atoms, to pierce a single graphene layer, according to scientists.

Led by physicist Andre Geim, awarded the Nobel in 2010 for his work on graphene, a research team set out to test whether protons, like atoms and molecules, would also be repelled by graphene. They “fully expected that protons would be blocked, as existing theory predicted as little proton permeation as for hydrogen,” said the statement.

“Despite the pessimistic prognosis, the researchers found that protons pass through the ultra-thin crystals surprisingly easily, especially at elevated temperatures…”

This made graphene an excellent candidate for proton-conducting membranes at the heart of fuel cell technology, said the statement.

Fuel cells, a kind of battery used in some electric cars and backup power generators, for example, use oxygen and hydrogen as a fuel and convert chemical energy into electricity. They require membranes that allow protons to pass through, but not other particles.

“It looks extremely simple and equally promising. Because graphene can be produced these days in square metre sheets, we hope that it will find its way to commercial fuel cells sooner rather than later,” said study co-author Sheng Hu.

Graphene was aired as a theoretical substance in 1947. But for decades, physicists thought it would be impossible to isolate, as such thin crystalline sheets were bound to be unstable.

The problem was resolved in 2004 by Geim and Konstantin Novoselov, who used ordinary sticky tape to lift a layer from a piece of graphite.

That layer was itself pulled apart using more tape, and the process repeated until just the thinnest of layers remained – a graphene sheet.


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